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The rotational barrier for methyl group dynamics in anhydrous sodium acetate

✍ Scribed by A.J. Moreno; A. Alegría; J. Colmenero; B. Frick

Book ID
106024891
Publisher
Springer
Year
2002
Tongue
English
Weight
290 KB
Volume
74
Category
Article
ISSN
1432-0630

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Rotational dynamics of the methyl group
Rotational dynamics of the methyl group in the 4-methyl pyridine crystal
✍ L. Soulard; F. Fillaux; G. Braathen; N. Le Calvé; B. Pasquier 📂 Article 📅 1986 🏛 Elsevier Science 🌐 English ⚖ 528 KB

Raman spectra below 150 cm-' of the 4-methyl pyridine crystal, and its deuterated derivative (d,), at various temperatures from 276.8 K (melting point) to 5 K are presented and vibrational assignments proposed. Three crystal phases are observed between 5-100 K (III), loo-254 K (II) and 254-276.8 K (