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The barriers to methyl group rotation in s-cis- and s-trans-methyl nitrite

✍ Scribed by Floyd R. Cordell; James E. Boggs

Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
697 KB
Volume
64
Category
Article
ISSN
0022-2860

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The two OH rotamers of 2-methyl-1-naphthol, syn-2M 1 HN and anti-2M 1 J-IN, have different CH, torsional barriers in both their ground and first excited electronic states, as revealed by high-resolution laser studies of their S,+S, fluorescence excitation spectra in a molecular beam. A comparison of