The rotameric distribution of 5-halomethyl groups in 1,3-dioxanes
β Scribed by Frans Borremans; Marc J.O. Anteunis
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 268 KB
- Volume
- 85
- Category
- Article
- ISSN
- 0037-9646
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π SIMILAR VOLUMES
## Abstract The molar Kerr constants and the dipole moments of __r__β2β__cis__β5βdimethylβ__trans__β5βΓΈβ1,3βdioxane (1), __r__;β2β__trans__β5βdimethylβ__cis__β5βΓΈβ1,3βdioxane (2), 2βmethylβ5,5βdiβΓΈβ1,3βdioxane (3), __cis__β2βmethylβ4βΓΈβ1,3βdioxane (4)β2β__cis__β6βdimethylβ__cis__β4βΓΈβ1,3βdioxane (5
The cyclic voltammetric and polarographic behavior of the title compounds (I)-(V) shows the formation of radical anions. On electroreduction these radical anions are cleaved under formation of the corresponding ketones.
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
5-Ethyl-1,3-dioxane-5-yl)methyl acrylate (HEDA) and (5-ethyl-1,3-dioxane-5-yl)methyl methacrylate (HEDMA) were synthesized by reaction between acryloyl and methacryloyl chloride with 5-ethyl, 5-hydroxymethyl, 1,3-dioxane. The kinetics of the polymerization of both are studied at different temperatur