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ChemInform Abstract: Electrolabile Protecting Groups for Ketones: The Electrochemical Reductive Cleavage of 1,3-Dioxolanes and 1,3-Dioxanes Containing Nitro Halo Groups.

✍ Scribed by R. LABRECQUE; J. MAILHOT; B. DAOUST; J. M. CHAPUZET; J. LESSARD


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis


The cyclic voltammetric and polarographic behavior of the title compounds (I)-(V) shows the formation of radical anions. On electroreduction these radical anions are cleaved under formation of the corresponding ketones.


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