The Role of Submarine Hydrothermal Systems in the Synthesis of Amino Acids
β Scribed by A. D. Aubrey; H. J. Cleaves; Jeffrey L. Bada
- Publisher
- Springer Netherlands
- Year
- 2008
- Tongue
- English
- Weight
- 335 KB
- Volume
- 39
- Category
- Article
- ISSN
- 1573-0875
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Hydrothermolysis of D-glucose, cellobiose, and fl-cyclodextrin leads to the formation of small amounts of 3-deoxyhexonic acids. These acids are known to be produced by the alkaline degradation of carbohydrates. The formation under neutral hydrothermal conditions of the 3-deoxyhexonic acids provides
Enamines 5 , prepared from heterocycles with a methyl group at a-position in respect to ring nitrogen atom 1 and N,N-dimethylformamide dimethyl acetal ( 3 ) or t-buthoxy-bis(dimethy1amino)methane (4), are transformed with 2-phenyl-5(4H)-oxazolone (1) into the corresponding intermediates 2, which cy