The role of singlet oxygen in bilirubin photo-oxidation
β Scribed by Antony F. McDonagh
- Book ID
- 119404977
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- English
- Weight
- 215 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0006-291X
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## Abstract In a two step reaction, hexamethylbenzene consumes two molecules of singlet oxygen to form epidioxy hydroperoxide **3**. The first step involves a [4 + 2]βcycloaddition, which is followed by an eneβreaction. The structure of the intermediary endoperoxide **2** has been established spect
Tetraphenylporphyrin-sensitized photo-oxidation of thiophenolates leads to the corresponding benzenesulfonates. The reaction proceeds via attack of singlet oxygen on the thiophenolate anion. A reaction mechanism is proposed. In view of the results of our investigations concerning the photo-oxidati