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Singlet-oxygen reactions in cyanoaromatic-sensitized photo-oxidations

✍ Scribed by Yi Cao; Bao Wen Zhang; Yang Fu Ming; Jian Xin Chen

Publisher
Elsevier Science
Year
1987
Weight
973 KB
Volume
38
Category
Article
ISSN
0047-2670

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Sensitized photo-oxidation of thiophenol
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✍ Simon J. Jongsma; Jan Cornelisse πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 French βš– 240 KB

Tetraphenylporphyrin-sensitized photo-oxidation of thiophenolates leads to the corresponding benzenesulfonates. The reaction proceeds via attack of singlet oxygen on the thiophenolate anion. A reaction mechanism is proposed. In view of the results of our investigations concerning the photo-oxidati