The role of quinidine in induction of asymmetric synthesis at mercury cathodes
β Scribed by E. Kariv; H.A. Terni; E. Gileadi
- Book ID
- 107748620
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- English
- Weight
- 894 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0013-4686
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This work describes preparative scale enantioselective cathodic reduction of some prochiral ketones, viz. 3,4-dihydro-1(2H)-naphthaleneone, 2-octanone, 1-phenyl-2-propanone, E-3-octen-2-one, 1-octyn-3-one, 1-undecyn-3-one, 1-tetradecyn-3-one at mercury pool in N,N-dimethyl formamide (DMF)-2-propanol
Recently, we have established that the electrochemical reduction of acyl halides in acetonitrile containing tetraalkylammonium salts can lead to the formation of aldehydes. Heptanoyl chloride is reduced to heptaldehyde at both carbon and mercury cathodes;' phenylacetaldehyde and hydroch~namaldehyde