## Abstract Two different mechanisms of inhibition of chemiluminescence in the oxidation of luminol by sodium hypochlorite were found. Most substances investigated in these experiments acted by scavenging NaOCI. This mechanism was independent of the concentration of hydrogen peroxide and the incuba
The role of nickel catalyst in the oxidation of diacetone-1-sorbose by sodium hypochlorite
✍ Scribed by A. Ujhidy; L. Markó; B. Babos
- Publisher
- Elsevier Science
- Year
- 1963
- Tongue
- French
- Weight
- 133 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0040-4039
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The ρ-value of -1.8 for the oxidation of para-substituted 1-phenylethanols by sodium hypochlorite in acetic acid suggests that ketone is formed directly from alcohol by loss of a hydride. The kinetic isotope effect is 3.0. When the disappearance of oxidant is followed by iodometric titration, 5-nona
Hydrogen peroxide amplifies the chemiluminescence in the odixation of luminol by sodium hypochlorite. A linear relationship between concentration of hydrogen peroxide and light intensity was found in the concentration range 5 x 10-\*-7.5 x mol/l. At 7.5 x l o -' mol/l H,Oz the chemiluminescence is a