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The Role of Metallacycles in the Chromium-Catalyzed Trimerization of Ethylene

✍ Scribed by Emrich, Rainer; Heinemann, Oliver; Jolly, Peter W.; Krüger, Carl; Verhovnik, Glenn P. J.

Book ID
123610405
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
78 KB
Volume
16
Category
Article
ISSN
0276-7333

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In this paper we report the results of an extensive experimental kinetic study carried out on the novel ethylene trimerization catalyst system, comprising the chromium source [CrCl(3)(thf)(3)] (thf=tetrahydrofuran), a Ph(2)P-N(iPr)-P(Ph)-N(iPr)H (PNPNH) ligand (Ph=phenyl, iPr=isopropyl), and triethy