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Role of MAO in Chromium-Catalyzed Ethylene Tri- and Tetramerization: A DFT Study

✍ Scribed by Janse van Rensburg, Werner; van den Berg, Jan-Albert; Steynberg, Petrus J.


Book ID
121380062
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
534 KB
Volume
26
Category
Article
ISSN
0276-7333

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PCNCP Ligands in the Chromium-Catalyzed
✍ Christian Klemps; Elina Payet; Lionel Magna; Lucien Saussine; Xavierβ€…F. Leβ€…Goff; πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 434 KB

## Abstract Chromium(III) complexes bearing Rβ€²N(CH~2~PR~2~)~2~ (PCNCP) ligands have been prepared. Upon activation with methylaluminoxane, these complexes proved to be effective in the selective tri‐ and tetramerization of ethylene. The formation of either 1‐hexene or 1‐octene was found to be highl