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A series of novel bisphosphinoamine ligands: Synthesis, characterization and application in ethylene tetramerization

โœ Scribed by Tao Jiang; HongXia Chen; ChenGang Cao; GuoLiang Mao; YingNan Ning


Book ID
107372298
Publisher
Springer
Year
2010
Tongue
English
Weight
529 KB
Volume
55
Category
Article
ISSN
1001-6538

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Novel chiral tridentate Schiff base liga
โœ Tatyana I. Danilova; Valeria I. Rozenberg; Elena V. Sergeeva; Zoya A. Starikova; ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 268 KB

The first example of the efficient application of chiral tridentate N,O-[2.2]paracyclophane ligands of the imino type for enantioselective diethylzinc addition to aliphatic and aromatic aldehydes is presented. The enantiomeric excess of the resulted secondary alcohols is up to 93% e.e.