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The Role of Ligand-Field States in the Ultrafast Photophysical Cycle of the Prototypical Iron(II) Spin-Crossover Compound [Fe(ptz) 6 ](BF 4 ) 2

✍ Scribed by Marino, Andrea; Chakraborty, Pradip; Servol, Marina; Lorenc, Maciej; Collet, Eric; Hauser, Andreas


Book ID
121690789
Publisher
John Wiley and Sons
Year
2014
Tongue
English
Weight
974 KB
Volume
53
Category
Article
ISSN
0044-8249

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πŸ“œ SIMILAR VOLUMES


Reversibility of light-induced excited s
✍ A. Hauser πŸ“‚ Article πŸ“… 1986 πŸ› Elsevier Science 🌐 English βš– 438 KB

Fe(ptz)6(BF4)2 (ptz = I-propyltetrazole) is an iron(H) spin-crossover system which shows light-Induced excited spin state trapping. In this paper we show that (a) the same phenomenon can also be observed in Zn, \_ rFeX(ptz)6(BF4)2 (x = 0.1) and is therefore basically a single-ion property, and (b) t