𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The role of inductive, hyperconjugative and d-orbital effects in organosilicon compounds

✍ Scribed by T. Veszprémi; J. Nagy

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
373 KB
Volume
255
Category
Article
ISSN
0022-328X

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Magnetic field-induced charge-density-wa
Magnetic field-induced charge-density-wave transitions: The role of the orbital and Pauli effects
✍ M.V. Kartsovnik; D. Andres; W. Biberacher; H. Müller 📂 Article 📅 2009 🏛 Elsevier Science 🌐 English ⚖ 403 KB

Due to a low transition temperature and, correspondingly, a small energy gap, the charge-density-wave (CDW) state of the layered organic metal a-ðBEDT-TTFÞ 2 KHgðSCNÞ 4 is very sensitive to pressure and magnetic field. The latter couples to the CDW via two competing mechanisms: Pauli paramagnetism a

Hydrogen abstraction from organosilicon
Hydrogen abstraction from organosilicon compounds. The reactions of fluoromethyl radicals with tetramethylsilane. Polar effects in gas phase reactions
✍ J. A. Kerr; D. M. Timlin 📂 Article 📅 1971 🏛 John Wiley and Sons 🌐 English ⚖ 634 KB

The photolysis of 1,1,3,3-tetrafluoroacetone has been reinvestigated as a source of CHFz radicals at temperatures up to 578'K, and the following rate constant ratio was determined for the reactions (8) (7) 2CHF2 -+ CHFzCHFz\* CHFz + CHFzCOCHFz -+ CHzFz + CF~COCHFZ log (k~/k~1'2)(mole-1'zcc1'2sec-1'2