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Inductive and hyperconjugative effects in the solvolysis of 4-substituted bicyclo[2.2.2]Oct-1-yl p-nitrobenzenesulfonates

✍ Scribed by C.A. Grob; R. Rich

Publisher
Elsevier Science
Year
1978
Tongue
French
Weight
164 KB
Volume
19
Category
Article
ISSN
0040-4039

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## Abstract The rate constants (log __k__) for the solvolysis of 4^e^‐substituted 2^e^‐ and 2^a^‐adamantyl __p__‐nitrobenzenesulfonates **14** and **15**, respectively, in 80% EtOH correlate linearly with the respective inductive substituent constants Οƒ. Therefore, relative rates are controlled by