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The Role of Hydrogen in the Pinacol Rearrangement of 2-Methyl-2,3-butanediol

โœ Scribed by Smith, William B.; Bowman, Richard E.; Kmet, Thomas J.

Book ID
126880238
Publisher
American Chemical Society
Year
1959
Tongue
English
Weight
889 KB
Volume
81
Category
Article
ISSN
0002-7863

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โœ Eric Loeser; Guang-Pei Chen; Tao He; Kapa Prasad; Oljan Repiฤ ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 180 KB

The reaction of 2,3-di-(3-pyridyl)-2,3-butanediol (1) in H 2 SO 4 was studied. It was found that the meso and racemic forms give mono-and bis-SO 3 addition products, which rearrange to a ketone (Metopirone ยฎ ) and two other major by-products. The formation of SO 3 addition products and a marked incr