The role of energy and entropy in the electrical double layer
โ Scribed by J. Theodoor; G. Overbeek
- Publisher
- Elsevier Science
- Year
- 1990
- Weight
- 499 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0166-6622
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๐ SIMILAR VOLUMES
A well-known charging process is used to obtain the free energy of an electrical double layer, in which the double layer is built up by a transfer of ions from one phase to another. The present study formulates proofs that this charging process cannot determine the free energy of an electrical doubl
Ever since values for the differential capacity of the electrical double layer have been available there have been speculations about the behaviour of the solvent in the interphase. Measurements using different solvents led Fmmkin I to the conclusion that the dielectric constant in the interphase di
Equation ( ) is arrived at by summing a geometric series in fl, i.e. 1 +fl+fl2+ ... ft,-l=(1-fl)-1 as n ~ m. When fl is 0.2, the series can be approximated by the first three terms.