The problem of structure and properties of the metal/salt melt interface has recently attracted the attention of numerous investigators 1,2. Significant information on this question may be obtained in two different ways : (a) by measuring the capacitance when the nature and composition of the metal
The electrical double layer in molten salts: Part 2. The double-layer capacitance
β Scribed by A.D. Graves; D. Inman
- Publisher
- Elsevier Science
- Year
- 1970
- Weight
- 941 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0022-0728
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β¦ Synopsis
Equation ( ) is arrived at by summing a geometric series in fl, i.e. 1 +fl+fl2+ ... ft,-l=(1-fl)-1 as n ~ m. When fl is 0.2, the series can be approximated by the first three terms.
π SIMILAR VOLUMES
It can be demonstrated that eqn. ( ) is identical to their eqn. (15) 4 by substituting their eqns. ( ), ( ) and ( ). U t in their eqn. ( ) is taken with a negative sign as it corresponds to the reverse process to that represented by as,. in eqn. (4) of this paper.
Ever since values for the differential capacity of the electrical double layer have been available there have been speculations about the behaviour of the solvent in the interphase. Measurements using different solvents led Fmmkin I to the conclusion that the dielectric constant in the interphase di