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The Role of Cytochrome b5in 4α-Methyl-Oxidation and C5(6) Desaturation of Plant Sterol Precursors

✍ Scribed by Alain Rahier; Mark Smith; Maryse Taton


Book ID
115580563
Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
104 KB
Volume
236
Category
Article
ISSN
0006-291X

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The Group 4 metallocene bis(enolate) complexes [Cp 2 M(-O-CMeCH 2 ) 2 ] (1) add one or two molar equivalents of the organometallic Lewis acid B(C 6 F 5 ) 3 to form the addition products (3), respectively. Complexes 3 a (M Ti) and 3 b (M Zr) were characterized by X-ray diffraction. Complexes 2 under