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The role of chelation in the formylation of grignard reagents with N-formyl amines.

✍ Scribed by Wimal Amaratunga; Jean M.J. Fréchet


Book ID
104220145
Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
216 KB
Volume
24
Category
Article
ISSN
0040-4039

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✦ Synopsis


The formylation of Grignard reagents with N-alkyl-N-formyl amines is best carried out


📜 SIMILAR VOLUMES


Aldehydes by Formylation of Grignard or
✍ Prof. Dr. George A. Olah; Mr. Massoud Arvanaghi 📂 Article 📅 1981 🏛 John Wiley and Sons 🌐 English ⚖ 262 KB 👁 1 views

dence for the rearrangement (2)+( 7). However, this isomerization can also be detected when (la) is used as starting material: Thus, on reaction of (la) with 6 equivalents of potassium tert-butoxide in THF at 35"C, the enol ether (10) is obtained in 44% yield. Its formation can be explained in terms