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Syntheses via-2-oxazolines. I. Formylation of Grignard reagents in the presence of hexamethylphosphoramide

✍ Scribed by Meyers, Albert I.; Collington, Eric W.

Book ID: 126048059
Publisher: American Chemical Society
Year: 1970
Tongue: English
Weight: 381 KB
Volume: 92
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00725a069

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## Catalytic Dechlorination of Aromatic Chlorides Using Grignard Reagents in the Presence of (C 5 H 5 ) 2 TiCl 2 . -The dechlorination of alkyl chlorides is also attempted under similar conditions. Thus, 1-chlorooctane gives octane in a moderate yield of 64% and isomers of octenes are detected as