✦ LIBER ✦

The role of bismuth in the SOHIO process

✍ Scribed by Tracy A. Hanna

Publisher: Elsevier Science
Year: 2004
Tongue: English
Weight: 238 KB
Volume: 248
Category: Article
ISSN: 0010-8545
DOI: 10.1016/j.ccr.2003.10.001

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✦ Synopsis

The Standard Oil of Ohio Company (SOHIO) process is the oxidation/ammoxidation of propene over bismuth/molybdate catalysts. Studies in the heterogeneous systems show that bismuth is involved in the rate-determining hydrogen abstraction from propene in both cases, and may be involved in later steps of the process as well. Model studies support the intervention of bismuth(III) in the rate-determining step and molybdenum(VI) in later steps. Few model studies with bismuth-containing compounds have been reported.

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