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The role of anomalous addition reactions in copolymerization processes

✍ Scribed by Lyubetzky, S. ;Goldenberg, A. ;Duntoff, F. ;Erussalimsky, B.


Publisher
Wiley (John Wiley & Sons)
Year
2007
Weight
266 KB
Volume
23
Category
Article
ISSN
0449-2994

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## Abstract A proline‐catalyzed asymmetric Michael addition between ketones and __trans__‐β‐nitrostyrene was studied by using the density‐functional theory with mPW1PW91 and B3LYP functionals. Improved insight into the enantio‐ and diastereoselective formation of γ‐nitroketones/‐aldehydes is obtain