The Role of Noninnocent Solvent Molecule
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Mahendra P. Patil; Raghavan B. Sunoj
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Article
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2008
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John Wiley and Sons
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English
⚖ 451 KB
👁 1 views
## Abstract A proline‐catalyzed asymmetric Michael addition between ketones and __trans__‐β‐nitrostyrene was studied by using the density‐functional theory with mPW1PW91 and B3LYP functionals. Improved insight into the enantio‐ and diastereoselective formation of γ‐nitroketones/‐aldehydes is obtain