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The role of amino acid residues in the active site of a midgut microvillar aminopeptidase from the beetle Tenebrio molitor

✍ Scribed by Plı́nio T Cristofoletti; Walter R

Book ID
114148697
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
309 KB
Volume
1479
Category
Article
ISSN
0167-4838

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Molecular orbital study of the effects of ionic amino acid residues on proton transfer energetics in the active site of carboxypeptidase a
✍ Setsuko Nakagawa; Hideaki Umeyama 📂 Article 📅 1981 🏛 Elsevier Science 🌐 English ⚖ 370 KB

As part of a study of the catalytic mechanism of carboxypeptidase A, two proton transfers in the system Glu 270-H20-Zn-His 69-Asp 142 are treated with an ab initio MO method. Results show that the proton transfers are strongly affected by the environment. It is predicted that the proton between His