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The ring opening of N-(1-phthalazyl)- and N-(4-quinazolyl)aziridines

✍ Scribed by Raymond N. Castle; Seiichi Takano


Book ID
112121703
Publisher
Journal of Heterocyclic Chemistry
Year
1968
Tongue
English
Weight
155 KB
Volume
5
Category
Article
ISSN
0022-152X

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ChemInform Abstract: Preparation and Rin
✍ A. A. CANTRILL; A. N. JARVIS; H. M. I. OSBORN; A. OUADI; J. B. SWEENEY πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 33 KB πŸ‘ 2 views

Preparation and Ring-Opening Reactions of N-Diphenylphosphinyl Vinyl Aziridines. -LDA-Lithiation of allyl bromide (I) followed by ZnCl2 generates Ξ± -bromo allyllithium which reacts with phosphinyl aldimines to form mainly trans-or cis-aziridines depending on the substituent R. The arylated trans-der