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The Reversible Thermal Decomposition of Triphenylmethylperoxy Radical to Triphenylmethyl Radical and Oxygen

โœ Scribed by Janzen, Edward G.; Johnston, F. J.; Ayers, Caroline L.

Book ID
121210195
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
1001 KB
Volume
89
Category
Article
ISSN
0002-7863

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Addition of methyl radicals to carbon mo
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โœ K. W. Watkins; William W. Word ๐Ÿ“‚ Article ๐Ÿ“… 1974 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 761 KB

## Abstract Chemically activated acetyl radicals, with an excitation energy of 78 kJ/mole, were formed by the addition of methyl radicals to carbon monoxide. At 273ยทK the pressure required to stabilize one half of the excited radicals was 500 torr. From measurements of the acetyl radical yield at p