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The resonance Raman excitation profile of fucoxanthin

✍ Scribed by L.J. Ballard; L.A. Glasgow; L.C. Hoskins; T. Krohe


Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
343 KB
Volume
45
Category
Article
ISSN
1386-1425

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✦ Synopsis


The resonance Raman excitation profiles (RREPs) of the v1 and v2 vibrations of fucoxanthin in acetone and toluene solvents have been studied. Fucoxanthin, which is a predominant pigment in marine seaweed and phytoplankton, has several structural differences from carotenoids for which excitation profiles have been determined. The RREPs for fucoxanthin are interpreted in terms of a two-mode model and show a B, value which is approximately 20% lower than for carotenoids like p-carotene and lutein which occur in higher plants. Excellent fits between experimental data and the theoretical model were observed in both solvents.


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