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The Relative Stability of Bridged Hydrocarbons. II. endo- and exo-Trimethylenenorbornane. The Formation of Adamantane 1,2

✍ Scribed by von R. Schleyer, Paul; Donaldson, Malcolm M.

Book ID
120308769
Publisher
American Chemical Society
Year
1960
Tongue
English
Weight
939 KB
Volume
82
Category
Article
ISSN
0002-7863

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## Abstract The behaviour of the regioselectively generated carbocation centers at C(2) and C(6) in 1,2‐trimethylenenorbornanes was investigated in order to study the occurrence or absence of a degenerate rearrangement **E⇄M** in the adamantane rearrangement of both 1,2‐__endo__‐ (**1**) and 1,2‐__