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The relative reactivity of thioethers and sulfoxides toward oxygen transfer reagents: the case of dioxiranes

✍ Scribed by Francesco P. Ballistreri; Gaetano A. Tomaselli; Rosa Maria Toscano; Marcella Bonchio; Valeria Conte; Fulvio Di Furia


Book ID
103402258
Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
214 KB
Volume
35
Category
Article
ISSN
0040-4039

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Thianthrene 5-oxide (SSO) constitutes a useful mechanistic tool for the assessment of the electronic character of oxygen transfer agents by means of their X,, values, which reflect the extent of nucleophilic oxidation at the SO site in SSO. Treatment of dioxiranes 1 a-d with the SSO probe confirms t