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The relative intensities of vibrational spectral bands in the .nu.(CO) region of [Os4O4(CO)12]

✍ Scribed by Jayasooriya, Upali A.; Anson, Christopher E.

Book ID: 126058510
Publisher: American Chemical Society
Year: 1986
Tongue: English
Weight: 469 KB
Volume: 108
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00271a018

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A detailed assignment of the v(C0) region of [Os,(CO),,] and [Ru~(CO),~] in the solid state is obtained by using relative intensities of these vibrational modes in the i.r. and Raman spectra. A qualitative intensity prediction is possible by recognizing that the real crystal structure of these solid