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The relationship of barrier shape to “linear” free energy slopes and curvatures

✍ Scribed by Joseph L. Kurz

Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
405 KB
Volume
57
Category
Article
ISSN
0009-2614

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✦ Synopsis

LeffIer's interpretation of linear free energy slopes is derivable from a general set of symmetric barrier functions. Marcus' rate equation is derivable from a subset of those barriers which includes E&art's barrier.

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