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The analysis of solvation in ionic liquids and organic solvents using the Abraham linear free energy relationship

✍ Scribed by William E Acree; Jr; Michael H Abraham

Publisher
Wiley (John Wiley & Sons)
Year
2006
Tongue
English
Weight
114 KB
Volume
81
Category
Article
ISSN
0268-2575

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✦ Synopsis

Abstract

The contentions made in an earlier paper [J Chem Technol Biotechnol 80: 133–137 (2005)] that the coefficients of the Abraham solvation equation do not provide meaningful information on the molecular properties of ionic liquid solvents is refuted. The objections noted in the earlier paper disappear when the solvation equation model is correctly applied to the experimental data. It is further shown that the coefficients of the Abraham solvation equations can be used to characterize ionic liquids and can be used to select solvents for the solubility of gaseous solutes. Copyright © 2006 Society of Chemical Industry

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