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The relationship between matrix elements of position and momentum in vibronic coupling

✍ Scribed by Gordon Hug; William Rhodes


Publisher
Elsevier Science
Year
1972
Tongue
English
Weight
203 KB
Volume
16
Category
Article
ISSN
0009-2614

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✦ Synopsis


A general expression is dcrivcd that relates the matrix elements of position and momenttim allolving for the possibility of a mixed basis. It is shown that when Born-Oppenhcimcr wavefunctions for IWO different clcctronic states arc used as basis functions, the use of the usual expression relating matris elements of position and momentum CXI lend to results that may not be of the correct order of magitude.


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