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The relationship between matrix elements of position and momentum in vibronic coupling: Chem. Phys. Letters 16 (1972) 399. f


Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
64 KB
Volume
19
Category
Article
ISSN
0009-2614

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The relationship between matrix elements
โœ Gordon Hug; William Rhodes ๐Ÿ“‚ Article ๐Ÿ“… 1972 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 203 KB

A general expression is dcrivcd that relates the matrix elements of position and momenttim allolving for the possibility of a mixed basis. It is shown that when Born-Oppenhcimcr wavefunctions for IWO different clcctronic states arc used as basis functions, the use of the usual expression relating ma