In the case of catalytic dehydrogenation of cyclohexane, the linear relation between reaction rate and affinity holds at an appreciable distance away from equilibrium on both sides. In fact, in order to explain this observation, it is necessary to invoke a high value of three for the stoichiometric
The relation between rate and affinity in carrier transports
β Scribed by Wilbrandt, Walther
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1956
- Tongue
- English
- Weight
- 334 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0095-9898
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β¦ Synopsis
The penetration of sugars across the human red cell membrane appears to be a complex process involving elements different from simple physical membrane diffusion. An interpretation assuming a carrier mechanism has been suggested by Le Fhvre. It was shown by this author as well as by Wilbrandt and Rosenberg and by Widdas that the penetration kinetics agree with the kinetics of a carrier transport under certain conditions.
The present paper deals with the dependence of the transport rate on the affinity to the components of the assumed carrier system (carrier and enzymes).
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