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Comments on the linear relation between reaction rate and affinity

✍ Scribed by Michel Boudart; Daniel G. Löffler; Juan Carlos Gottifredi

Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
228 KB
Volume
17
Category
Article
ISSN
0538-8066

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✦ Synopsis

In the case of catalytic dehydrogenation of cyclohexane, the linear relation between reaction rate and affinity holds at an appreciable distance away from equilibrium on both sides. In fact, in order to explain this observation, it is necessary to invoke a high value of three for the stoichiometric number of the rate determining step. This in turn can be explained by a reasonable mechanism for the reaction.

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