The very low pressure reactor (VLPR) technique has been used to measure the bimolecular rate constant of the title reaction at 300 K. The rate constant is given by log k, (l/mol s) = (11.6 2 0.4) -(5.9 ? 0.6)/0 the equilibrium constant has also been measured at the same temperature and is given by K
The Reinvestigation of the Kinetics of the Metathesis Reactions t-C 4 H 9• + HBr (HI) → i-C 4 H 10 + Br • (I • ) and of the t-C 4 H 9• Free Radical Thermochemistry
✍ Scribed by Leplat, N.; Rossi, M. J.
- Book ID
- 127289461
- Publisher
- American Chemical Society
- Year
- 2014
- Tongue
- English
- Weight
- 758 KB
- Volume
- 118
- Category
- Article
- ISSN
- 1089-5639
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The Arrhenius parameters for the title reaction have been measured in a very-low-pressure pyrolysis apparatus in the temperature range 644-722 K and are given by log kZ (A4-I. sec-I) = 9.68 -2.12/8, where 0 = 2.303RT in kcal/mol. Together with the published Arrhenius parameters for the reverse react
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