𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The Reinvestigation of the Kinetics of the Metathesis Reactions t-C 4 H 9• + HBr (HI) → i-C 4 H 10 + Br • (I • ) and of the t-C 4 H 9• Free Radical Thermochemistry

✍ Scribed by Leplat, N.; Rossi, M. J.


Book ID
127289461
Publisher
American Chemical Society
Year
2014
Tongue
English
Weight
758 KB
Volume
118
Category
Article
ISSN
1089-5639

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Rates and equilibria in the reaction sys
✍ Tajmeri S. A. Islam; Sidney W. Benson 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 English ⚖ 635 KB

The very low pressure reactor (VLPR) technique has been used to measure the bimolecular rate constant of the title reaction at 300 K. The rate constant is given by log k, (l/mol s) = (11.6 2 0.4) -(5.9 ? 0.6)/0 the equilibrium constant has also been measured at the same temperature and is given by K

The rate constant for t-C4H9 → H + i-C4H
✍ Carlos E. Canosa; Roger M. Marshall 📂 Article 📅 1981 🏛 John Wiley and Sons 🌐 English ⚖ 565 KB

## Abstract The rate of the reverse reaction of the system equation image has been measured in the range of 584–604 K from a study of the azomethane sensitized pyrolysis of isobutane. Assuming the published value for the rate constant of recombination of __t__‐butyl we obtain Combination with o

The absolute rate constant for the metat
✍ Michel Rossi; David M. Golden 📂 Article 📅 1979 🏛 John Wiley and Sons 🌐 English ⚖ 419 KB 👁 1 views

The Arrhenius parameters for the title reaction have been measured in a very-low-pressure pyrolysis apparatus in the temperature range 644-722 K and are given by log kZ (A4-I. sec-I) = 9.68 -2.12/8, where 0 = 2.303RT in kcal/mol. Together with the published Arrhenius parameters for the reverse react

Laser-induced kinetics: Arrhenius parame
✍ M. J. Rossi; D. M. Golden 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 English ⚖ 886 KB

The metathesis reaction of DI with t X4H9 generated by 351-nm photolysis of 2,2'-azoisopropane was studied in a low-pressure reactor (VLP@ Knudsen cell) in the temperature range of 302-411 K. The data obeyed the following Arrhenius relation when combined with recent data by Rossi and Golden gathered