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The Regioselectivity of Addition of Organolithium Reagents to Enones and Enals: The Role of HMPA

✍ Scribed by Sikorski, William H.; Reich, Hans J.

Book ID
121238146
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
137 KB
Volume
123
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

Addition of organolithium reagents to th
Addition of organolithium reagents to the double bond of allylic alcohols
✍ Hugh Felkin; GΓ©rard Swierczewski; AndrΓ© TambutΓ© πŸ“‚ Article πŸ“… 1969 πŸ› Elsevier Science 🌐 French βš– 224 KB

Reactive (ally1 and benzyl) Grignard reagents have been shorn to add to the double bond of allylic alcohols (I; Rv = H or Ar); the intermediates foraed in this reaction are probably the cyclic adducts II, vhich are themselves Grignard reagents and lead to a variety of products when treated vith suit