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THE REGIOSELECTIVE NITRATION OF α,β-UNSATURATED NITRILES WITH NITROGEN OXIDES

✍ Scribed by Navarro-Ocaña, Arturo; Barzana, Eduardo; López-González, Daniel; Jiménez-Estrada, Manuel

Book ID
120179809
Publisher
Taylor and Francis Group
Year
1999
Tongue
English
Weight
184 KB
Volume
31
Category
Article
ISSN
0030-4948

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✍ Jiro Tsuji; Hiroaki Ueno; Yuichi Kobayashi; Hiroshi Okumoto 📂 Article 📅 1981 🏛 Elsevier Science 🌐 French ⚖ 120 KB

e-Acetoxy-8,y-unsaturated nitriles react at room temperature with malonates and acetoacetates in the presence of palladium-phosphine complexes as a catalyst to give y-substituted a,8-unsaturated nitriles selectively. Also yacetoxy-a,8-unsaturated ester was attacked at y-position by malonate.