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The regioselective oxidation of 1-trimethylsilycyclopropenes to α-trimethylsilyl-α,β,- unsaturated ketones

✍ Scribed by Mark S. Baird; Helmi H. Hussain


Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
226 KB
Volume
27
Category
Article
ISSN
0040-4039

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The addition of trimethylsilyl iodide to
✍ R.D. Miller; D.R. McKean 📂 Article 📅 1979 🏛 Elsevier Science 🌐 French ⚖ 234 KB

Haloketones and derivatives are extremely useful materials for Organic Synthesis. We describe here the facile preparation of S and y-iodoketones by the addition of trimethylsilyl iodide to a variety of a,S-unsaturated and cyclopropyl ketones. S-Haloketones are useful substrates in Organic Synthesis