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The Regiochemistry of Carbenoid Insertion into Zirconacycles

✍ Scribed by George J. Gordon; Tim Luker; Mark W. Tuckett; Richard J. Whitby

Book ID
104209841
Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
943 KB
Volume
56
Category
Article
ISSN
0040-4020

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Metallated epoxides (epoxysilanes, epoxynitriles, epoxystyrene) insert eciently into zirconacycles via a 1,2-metallate rearrangement to form intermediates which eliminate Cp 2 Zr(R)O ^to aord substituted alkenes.