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Insertion of metallated epoxides into zirconacycles

✍ Scribed by Alexander N. Kasatkin; Richard J. Whitby

Book ID
104210489
Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
224 KB
Volume
41
Category
Article
ISSN
0040-4039

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✦ Synopsis

Metallated epoxides (epoxysilanes, epoxynitriles, epoxystyrene) insert eciently into zirconacycles via a 1,2-metallate rearrangement to form intermediates which eliminate Cp 2 Zr(R)O ^to aord substituted alkenes.

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