The Reformatsky Reaction: Effect of Alkyl Group in Alkyl α-Bromopropionates
✍ Scribed by Newman, Melvin S.; Evans, F. James
- Book ID
- 125985446
- Publisher
- American Chemical Society
- Year
- 1955
- Tongue
- English
- Weight
- 270 KB
- Volume
- 77
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Tandem aldol-like reactions are accessible through the addition of the Reformatsky reagent derived from 2-bromopropionate to either formate /eq 2/ or orthoformate /eq 3/ accep-tor in the presence of chlorotrimethylsilane. In recent years, as a result of extensive investigations, we have witnessed ex
Recent insights (1) in the remarkable solvent properties of dimethyl eulfoxida (DMSO), and our own interest in the chemistry of isopropcnyl ethers (2) led u8 to consider the poraibility of direot 0-alkylation of ethyl aoetoaoetate in that solvent. The connection i# that Kornblum'rr work (3) suggests