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The reduction of α-ketocarboxylic acids and α-dicarbonyl compounds with titanium(III) chloride

✍ Scribed by Hugh A. Akers; Joseph G. Abdo; Cynthia Hamilton


Book ID
107714259
Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
350 KB
Volume
154
Category
Article
ISSN
0003-2697

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The reduction of hydroxamic acids with t
✍ David J. Kushner; Todd A. Landry; Mary C. Tyrrell; Hugh A. Akers 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 316 KB

Hydroxamic acid siderophores were observed to be inactivated by exposure to titanium(III) chloride. To study the reaction, a series of eight model hydroxamic acids were prepared and reacted with titanium(III) chloride. The products were shown by ir and NMR comparisons with authentic compounds to be