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The reduction of hydroxamic acids with titanium(III) chloride: A tool for the characterization of siderophores

โœ Scribed by David J. Kushner; Todd A. Landry; Mary C. Tyrrell; Hugh A. Akers

Book ID
102629680
Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
316 KB
Volume
133
Category
Article
ISSN
0003-2697

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โœฆ Synopsis

Hydroxamic acid siderophores were observed to be inactivated by exposure to titanium(III) chloride. To study the reaction, a series of eight model hydroxamic acids were prepared and reacted with titanium(III) chloride. The products were shown by ir and NMR comparisons with authentic compounds to be the corresponding amides. The reduction was found to require 2 mol of titanium(III) per mol of hydroxamic acid.

๐Ÿ“œ SIMILAR VOLUMES

The reduction of aliphatic and aromatic
The reduction of aliphatic and aromatic N-oxides to the corresponding amines with titanium(III) chloride
โœ Quirt F. Seaton; Cheryl W. Lawley; Hugh A. Akers ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 303 KB

Amine N-oxides have been observed to be reduced by titanium(II1) chloride. To study this reaction, 24 model amine N-oxides were reacted with titanium(II1) chloride. The products of these reactions were shown by melting (boiling) points, mixed melting points, derivatives, refractive indices, infrared