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The Reduction of α-Diketones

✍ Scribed by Thompson, R. B.


Book ID
126290148
Publisher
American Chemical Society
Year
1939
Tongue
English
Weight
289 KB
Volume
61
Category
Article
ISSN
0002-7863

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Indium-Mediated Regio- and Diastereosele
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## Abstract A novel, efficient, and regio‐ as well as diastereoselective conversion of non‐enolizable bicyclic α‐diketones into synthetically useful acyloins mediated by indium metal is described. The reduction is highly diastereoselective, leading exclusively to __endo__‐acyloins (__endo__‐hydroxy