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The Recombination of Atoms. II. Causes of Variation in the Observed Rate Constant for Iodine Atoms

✍ Scribed by Christie, M. I.; Harrison, A. J.; Norrish, R. G. W.; Porter, G.

Book ID: 120146074
Publisher: The Royal Society
Year: 1955
Tongue: English
Weight: 578 KB
Volume: 231
Category: Article
ISSN: 0962-8444
DOI: 10.1098/rspa.1955.0186

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The recombination of iodine atoms following the flash photolysis of iodine in the presence of nitric oxide is interpreted through the mechanism ki k-i with k~ = 3.5 X lo9 1.2/rno12-sec; kz = 1 X 10" l./rnol.sec; k3 = 2.1 X LO7 l./mol-sec at 298°K; E3 = 11 kJ/ rnol; and AH"] = 76 f 6 kJ/mol. Lower a