𝔖 Bobbio Scriptorium
✦   LIBER   ✦

THE REARRANGEMENT OF THE NEOPHYL RADICAL

✍ Scribed by Seubold, Frank H.

Book ID
126117913
Publisher
American Chemical Society
Year
1953
Tongue
English
Weight
283 KB
Volume
75
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Observation of the Neophyl Radical Rearr
Observation of the Neophyl Radical Rearrangement by Electron Spin Resonance Spectroscopy
✍ Edwin J. Hamilton Jr.; Hanns Fischer πŸ“‚ Article πŸ“… 1973 πŸ› John Wiley and Sons 🌐 German βš– 277 KB

## Abstract The rearrangement of the 2‐methyl‐2‐phenylpropyl (or neophyl) radical **1** to the 1‐methyl‐1‐benzylethyl radical **2** is observed by ESR. spectroscopy during photolysis of di‐__t__‐butylperoxide in __t__‐butylbenzene at 270–360 K. The energy of activation of the rearrangement is deter