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The rearrangement of tertiary propargyl alcohols to α,β-unsaturated aldehydes in the presence of polymeric organosilyl vanadates.

✍ Scribed by M.B. Erman; I.S. Aul'chenko; L.A. Kheifits; V.G. Dulova; Ju.N. Novikov; M.E. Vol'pin


Book ID
104237225
Publisher
Elsevier Science
Year
1976
Tongue
French
Weight
269 KB
Volume
17
Category
Article
ISSN
0040-4039

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The Rearrangement of α-Acetylenic Alcoho
✍ Horst Pauling; David Arthur Andrews; Nathan Chadwick Hindley 📂 Article 📅 1976 🏛 John Wiley and Sons 🌐 German ⚖ 741 KB

## Abstract New catalytic systems have been found which effect the isomerization of α‐acetylenic alcohols to the corresponding α, β‐unsaturated carbonyl compounds with high efficiency. These are combinations of silylvanadates with silanols or silanediols.