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The Rearrangement of α-Acetylenic Alcohols to α, β-Unsaturated Carbonyl Compounds by Silylvanadate Catalysts

✍ Scribed by Horst Pauling; David Arthur Andrews; Nathan Chadwick Hindley

Publisher: John Wiley and Sons
Year: 1976
Tongue: German
Weight: 741 KB
Volume: 59
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.19760590426

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✦ Synopsis

Abstract

New catalytic systems have been found which effect the isomerization of α‐acetylenic alcohols to the corresponding α, β‐unsaturated carbonyl compounds with high efficiency. These are combinations of silylvanadates with silanols or silanediols.

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